肖学章

中山大学教授，博士生导师

办公地址：中山大学深圳校区工学园1栋616室

工作邮箱：xiaoxzh6@mail.sysu.edu.cn

研究领域：新能源储存转化材料、机器学习设计新型储能材料、氢储能材料与工程技术、氢同位素储存供给技术、加氢站固态储供氢装置、氢电融合调能系统集成

个人简介

肖学章教授长期从事氢储能材料与工程技术、固态储氢系统以及氢电融合系统集成的应用基础研究，主要研究包括：（1）提出功能化石墨烯/碳纳米管的原位界面纳米限域储氢材料新方法，构建硼氢化物复合储氢新体系，实现高密度氢化物的近室温吸放氢和数量级放氢动力学提升；（2）创建高组态熵储氢合金设计新策略，实现材料吸放氢全过程的同晶型转变，有效抑制吸放氢歧化反应并大幅提高合金可逆储氢循环稳定性，并应用于氢同位素贮存与供给原型系统样机；（3）提出基于机器学习模型的储氢材料高通量设计新范式，突破静态氢压缩装置多级联用耦合瓶颈，实现具有我国优势资源的稀土/钛基氢压缩储氢材料集成匹配，开发出自主知识产权的快响应金属储供氢材料并用于静态氢压缩系统的核心装置部件，助力我国首次实现固态氢能发电并网，同时成功应用于35MPa/70MPa加氢站用固态储供氢装置。

作为负责人先后承担国家自然科学基金重点项目课题1项，国家自然科学基金项目3项，国家重点研发计划课题1项、子课题3项，国家973项目子课题1项，国家863项目子课题1项，以及浙江省自然科学基金重点项目，浙江省重点科技创新团队项目，浙江省公益性技术应用研究计划等20余项。在Nature、Nature Energy、Nature Chemistry、Nature Communications、Advanced Materials、Energy Storage Mater、Nano Energy等先进能源&材料领域期刊上发表研究论文200余篇，其中第一/通讯作者160多篇，同时以通讯作者获邀在Progress in Materials Science、Energy & Environmental Science、Advanced Materials等顶级期刊发表多篇氢能综述论文，个人H因子45，获授权国家发明专利35项。在首届世界能源材料大会、国际先进能源材料研讨会、世界燃料电池大会、中国氢能科学技术和工程大会、中国材料大会等国内外学术会议作邀请报告20余次，兼任国际著名金属材料期刊Journal of Alloys and Compounds副主编、国际镁合金期刊Journal of Magnesium and Alloys青年编委、中国可再生能源学会氢能专业委员会委员、中国动力工程学会工业气体专业委员会委员和浙江省能源研究会储能技术专业委员会秘书长。

教育工作经历

2024.11-至今，中山大学, 先进能源学院, 教授/博士生导师、副院长、专任教师党支部书记

2014.07-2024.10，浙江大学, 材料科学与工程学院, 副教授/博士生导师、金属所实验室主任

2013.10-2014.10，英国格拉斯哥大学, 化学学院, Academic Visitor

2011.12-2012.05，美国西弗吉尼亚大学, 机械与航天航空工程学系, Reserach Scientist

2010.08-2014.06，浙江大学, 材料科学与工程学系, 讲师/副教授/硕士生导师

2008.06-2010.07，浙江大学，化学工程与技术流动站, 博士后

2003.09-2008.06，浙江大学, 材料科学与工程, 获工学博士学位

1999.09-2003.06，中南大学, 材料物理, 获学士学位

主持科研项目

1. 海况条件对氢能高安全储-运-加系统的影响规律及创新设计，国家科技部(国家重点研发计划课题)，2024-12至2027-11

2. 固态储氢系统集成优化及全工况氢热耦合研究，国家科技部(国家重点研发计划子课题)，2022-11至2026-11

3. 基于碳负载金属硼氢化物储氢体系的吸放氢热力学与动力学双调控机制，国家自然科学基金委员会，2022-01至2025-12

4. 基于高压气固新型复合储氢材料体系的创制以及吸放氢性能调控机理，浙江省基金委(重点项目)，2021-01至2023-12

5. ZrCo、Pd和U基贮氚材料氢化反应活性的表界面调控及机理研究，国家自然科学基金委员会(NSAF联合重点项目课题)，2021-01至2024-12

6. 静态氢压缩装置设计和制备技术, 国家科技部(国家重点研发计划课题子)，2019-12至2022-11

7. 不可逆氢化物可控催化放氢动力学及高集成度放氢系统的构建，国家科技部(国家重点研发计划子课题)，2019-04至2022-03

8. 过渡金属硼化物非晶超细颗粒的可控制备及其对轻金属硼氢化物可逆储氢的催化改性机理，国家自然科学基金委员会，2016-01至2019-12

9. 车载燃料电池用纳米配位铝氢化物储氢材料的制备与中低温吸放氢关键技术研究，浙江省科技厅(省公益性技术应用研究计划项目)，2015-01至2016-12

10. 高容量金属锂基配位氢化物复合储氢材料体系的研究，浙江省科技厅(省重点科技创新团队项目)，2011-01至2014-12

11. 加氢站用固态/高压混合储氢技术，国家科技部(863计划子课题)，2012-01至2014-12

12. LiBH4体系的可逆吸放氢性能研究，国家科技部(973计划子课题)，2010-01至2014-12

13. 新型双金属复合配位硼氢化物体系的吸/放氢热力学和动力学研究，国家自然科学基金委员会，2011-01至2013-12

代表论文

ORCID ID https://orcid.org/0000-0003-4035-5044

1. F. Chu, J. He, J. Wang, N. Lei, S. Yuan, S. Zhang, L. Chen, X. Xiao*: Medium-entropy alloy design enables highly efficient catalytic methanolysis of ammonia borane.

Applied Catalysis B: Environment and Energy 2025, 368:125140.

2. T. Zhang, M. Liu, C. Li, J. Zhang, H. Gao, F. Kong, X. Xiao*: Synergistic catalysis of YF3 and Ni/C: Exceptional effects on hydrogen storage performances of MgH2 at low temperature.

Chemical Engineering Journal 2025, 511:162185.

3. Q. Zhou, P. Zhou, J. Bi, L. Zhang, S. Xiao, X. Xiao*, X. Fan, L. Chen: Micro-alloying design-enabled surface activity engineering for enhanced anti-poisoning properties of ZrCo-based hydrogen isotope storage materials.

Journal of Energy Chemistry 2025, 188:254-262.

4. J. Qi, X. Zhang, B. Yu, X. Xiao*, F. Chu, T. Ying, X. Feng, J. Song, Y. Shi, H. Kou, C. Chen, W. Luo, L. Chen, Isostructural Transition of Zr0.Hf.Nb.Co.Cu.Ni.25 Alloy for Isotope Trapping Minimization and High-Temperature Durability Enhancement.

Energy Environ. Mater. 2025, e70000.

5. J.-R. Zhang, Y.-Q. Jia, F. Chu, N. Lei, J.-P. Bi, H.-Y. Qin, M.-L. Liu, Y.-X. Jia, L. Zhang, L. Jiang, L.-Z. Ouyang, X.-Z. Xiao*: Carbothermal shock fabrication of CoO-Cu2O nanocomposites on N-doped porous carbon for enhanced hydrolysis of ammonia borane.

Rare Metals 2025, doi.org/10.1007/s12598-025-03290-2.

6. R Li, X Huang, H Zhang, J Wang, Y Fan, Y Huang, J Liu, M Yang, Y Yu, X Xiao, Y Tan, H Wu, L Fan, T Deng, L Chen, Y Shen, X Fan. A path towards high lithium-metal electrode coulombic efficiency based on electrolyte interaction motif descriptor.

Nature Communications 2025, 16:4672.

7. Zhou P, Zhou Q, Xiao X*, Fan X, Zou Y, Sun L, Chen L: Machine Learning in Solid-State Hydrogen Storage Materials: Challenges and Perspectives.

Advanced Materials 2025, 37:2413430.

8. Zhang J, Liu M, Qi J, Lei N, Guo S, Li J, Xiao X*, Ouyang L: Advanced Mg-based materials for energy storage: fundamental, progresses, challenges and perspectives.

Progress in Materials Science 2025, 148:101381.

9. Zhang Y, Zhou P, Xiao X*, Bi J, Zhang X, Kou H, Huang X, Tang T, Chen L: Superior oxygen-resistance and intrinsic mechanisms of coherent Pd/Pd3Zr@ZrCo structure with excellent cycling durability.

Chemical Engineering Journal 2024, 479:147660.

10. Qi J, Huang X, Xiao X*, Zhang X, Zhou P, Zhang S, Li R, Kou H, Jiang F, Yao Y et al: Isotope engineering achieved by local coordination design in Ti-Pd co-doped ZrCo-based alloys.

Nature Communications 2024, 15(1):2883.

11. Ma B, Zhang H, Li R, Zhang S, Chen L, Zhou T, Wang J, Zhang R, Ding S, Xiao X et al: Molecular-docking electrolytes enable high-voltage lithium battery chemistries.

Nature Chemistry 2024, 16:1427–1435.

12. Lu D, Li R, Rahman MM, Yu P, Lv L, Yang S, Huang Y, Sun C, Zhang S, Zhang H, Zhang J, Xiao X et al: Ligand-channel-enabled ultrafast Li-ion conduction.

Nature 2024, 627(8002):101-107.

13. Jia Y, Zhou P, Xiao X*, Wang X, Han B, Wang J, Xu F, Sun L, Chen L: Synergetic action of 0D/2D/3D N-doped carbon nanocages and NbB2 nanocatalyst on reversible hydrogen storage performance of lithium borohydride. Chemical Engineering Journal 2024, 485:150090.

14. Jia Y, Han B, Wang J, Yuan S, Tang L, Zhang Z, Zou Y, Sun L, Du Y, Chen L, Xiao X*: Inducing One-Step Dehydrogenation of Magnesium Borohydride via Confinement in Robust Dodecahedral Nitrogen-Doped Porous Carbon Scaffold.

Advanced Materials 2024:2406152.

15. Bi J, Zhou P, Xiao X*, Zhang Y, Kou H, Tang T, Chen L: General impurity gas blanket effect mechanism and elimination strategies for hydrogen storage materials.

Chemical Engineering Journal 2024, 481:148517.

16. Bi J, Zhou P, Jiang W, Kou H, Tang T, Zhang Y, Liu Y, Zhou Q, Yao Y, Zhang Y, Xiao X*: Poisoning Mechanism Map for Metal Hydride Hydrogen Storage Materials.

Advanced Science 2024, 20:2408522.

17. Zhou P, Zhang J, Bi J, Xiao X*, Cao Z, Zhan L, Shen H, Lu M, Li Z, Zhao Y et al: Underlying factors of mega pressure hysteresis in cerium-rich CaCu5-type metal hydrides and effective modification strategies.

Journal of Materials Chemistry A 2023, 11(47):25963-25972.

18. Zhou P, Xiao X*, Zhu X, Chen Y, Lu W, Piao M, Cao Z, Lu M, Fang F, Li Z et al: Machine learning enabled customization of performance-oriented hydrogen storage materials for fuel cell systems.

Energy Storage Mater 2023, 63:102964.

19. Zhou P, Cao Z, Xiao X*, Zhan L, He J, Zhao Y, Wang L, Yan M, Li Z, Chen L: Development of RE-based and Ti-based multicomponent metal hydrides with comprehensive properties comparison for fuel cell hydrogen feeding system.

Materials Today Energy 2023, 33:101258.

20. Zhan L, Cao Z, Piao M, Xiao X*, Zhou P, Chen Y, Li Z, Jiang L, Li Z, Chen L: Experimental and numerical study of metal hydride beds with Ti0.92Zr0.10Cr1.0Mn0.6Fe0.4 alloy for hydrogen compression.

Chemical Engineering Journal 2023, 474:145654.

21. Wei J, Chen H, He J, Huang Z, Qin H, Xiao X*, Ni H, Chi H, He J: Cobalt-based N-doped bamboo-like graphene tubes with enhanced durability for efficient oxygen reduction reaction in direct borohydride fuel cell.

Carbon 2023, 201:856-863.

22. Wang X, Jia Y, Xiao X*, Zhou P, Bi J, Qi J, Lv L, Xu F, Sun L, Chen L: Robust architecture of 2D nano Mg-based borohydride on graphene with superior reversible hydrogen storage performance.

Journal of Materials Science & Technology 2023, 146:121-130.

23. Qi J, Liang Z, Xiao X*, Yao Z, Zhou P, Li R, Lv L, Zhang X, Kou H, Huang X et al: Effect of isostructural phase transition on cycling stability of ZrCo-based alloys for hydrogen isotopes storage.

Chemical Engineering Journal 2023, 455:140571.

24. Jia Y, Wang X, Hu L, Xiao X*, Zhang S, He J, Qi J, Lv L, Xu F, Sun L et al: Carbon composite support improving catalytic effect of NbC nanoparticles on the low-temperature hydrogen storage performance of MgH2.

Journal of Materials Science & Technology 2023, 150:65-74.

25. He J, Zhou P, Xiao X*, Chu F, Ouyang L, Liu B, Li R, Huang Z, Hu L, Yuan S et al: Coupling architectural and electronic engineering over cobalt molybdenum intermetallic compound for boosting hydrogen generation from ammonia borane.

Chemical Engineering Journal 2023, 474:145604.

26. Zhang X, Xiao X*, Chen J, Liu Y, Pan H, Sun W, Gao M: Toward the fast and durable alkaline hydrogen oxidation reaction on ruthenium.

Energy & Environmental Science 2022, 15(11):4511-4526.

27. Wang X, Xiao X*, Liang Z, Zhang S, Qi J, Lv L, Piao M, Zheng J, Chen L: Ultrahigh reversible hydrogen capacity and synergetic mechanism of 2LiBH4-MgH2 system catalyzed by dual-metal fluoride.

Chemical Engineering Journal 2022, 433:134482.

28. Liang Z, Yao Z, Li R, Xiao X*, Ye Z, Wang X, Qi J, Bi J, Fan X, Kou H et al: Regulating local chemistry in ZrCo-based orthorhombic hydrides via increasing atomic interference for ultra-stable hydrogen isotopes storage.

Journal of Energy Chemistry 2022, 69:397-405.

29. He J, Huang Z, Chen W, Xiao X*, Yao Z, Liang Z, Zhan L, Lv L, Qi J, Fan X et al: 0D/1D/2D Co@Co2Mo3O8 nanocomposite constructed by mutual-supported Co2Mo3O8 nanosheet and Co nanoparticle: Synthesis and enhanced hydrolytic dehydrogenation of ammonia borane.

Chemical Engineering Journal 2022, 431:133697.

30. Zheng J, Wang X, Xiao X*, Cheng H, Zhang L, Chen L: Improved reversible dehydrogenation properties of Mg(BH4)2 catalyzed by dual-cation transition metal fluorides K2TiF6 and K2NbF7.

Chemical Engineering Journal 2021, 412:128738.

31. Liang Z, Yao Z, Xiao X*, Wang X, Kou H, Luo W, Chen C, Chen L: Positive impacts of tuning lattice on cyclic performance in ZrCo-based hydrogen isotope storage alloys.

Materials Today Energy 2021, 20:100645.

32. Zhang M, Xiao X*, Luo B, Liu M, Chen M, Chen L: Superior de/hydrogenation performances of MgH2 catalyzed by 3D flower-like TiO2@C nanostructures.

Journal of Energy Chemistry 2020, 46:191-198.

33. Yao Z, Xiao X*, Liang Z, Huang X, Kou H, Luo W, Chen C, Chen L: An in-depth study on the thermodynamics and kinetics of disproportionation behavior in ZrCo–H systems.

Journal of Materials Chemistry A 2020, 8(18):9322-9330.

34. Yao Z, Liang Z, Xiao X*, Huang X, Liu J, Wang X, Zheng J, Kou H, Luo W, Chen C et al: An impact of hydrogenation phase transformation mechanism on the cyclic stabilizing behavior of Zr0.8Ti0.2Co alloy for hydrogen isotope handling.

Materials Today Energy 2020, 18:100554.

35. Wang X, Xiao X*, Zheng J, Yao Z, Zhang M, Huang X, Chen L: Insights into magnesium borohydride dehydrogenation mechanism from its partial reversibility under moderate conditions.

Materials Today Energy 2020, 18:100552.

36. Lin W, Xiao X*, Wang X, Wong J-W, Yao Z, Chen M, Zheng J, Hu Z, Chen L: Extreme high reversible capacity with over 8.0 wt% and excellent hydrogen storage properties of MgH2 combined with LiBH4 and Li3AlH6.

Journal of Energy Chemistry 2020, 50:296-306.

37. Huang X, Xiao X*, He Y, Yao Z, Ye X, Kou H, Chen C, Huang T, Fan X, Chen L: Probing an intermediate state by X-ray absorption near-edge structure in nickel-doped 2LiBH4–MgH2 reactive hydride composite at moderate temperature.

Materials Today Nano 2020, 12:100090.

38. Chen M, Xiao X*, Zhang M, Mao J, Zheng J, Liu M, Wang X, Chen L: Insights into 2D graphene-like TiO2(B) nanosheets as highly efficient catalyst for improved low-temperature hydrogen storage properties of MgH2.

Materials Today Energy 2020, 16:100411.

39. Chen M, Xiao X*, Wang X, Lu Y, Zhang M, Zheng J, Chen L: Self-templated carbon enhancing catalytic effect of ZrO2 nanoparticles on the excellent dehydrogenation kinetics of MgH2.

Carbon 2020, 166:46-55.

40. Zhang M, Xiao X*, Mao J, Lan Z, Huang X, Lu Y, Luo B, Liu M, Chen M, Chen L: Synergistic catalysis in monodispersed transition metal oxide nanoparticles anchored on amorphous carbon for excellent low-temperature dehydrogenation of magnesium hydride.

Materials Today Energy 2019, 12:146-154.

41. Liu MJ, Zhao SC, Xiao XZ*, Chen M, Sun CH, Yao ZD, Hu ZC, Chen LX: Novel 1D carbon nanotubes uniformly wrapped nanoscale MgH2 for efficient hydrogen storage cycling performances with extreme high gravimetric and volumetric capacities.

Nano Energy 2019, 61:540-549.

42. Fan XL, Ji X, Chen L, Chen J, Deng T, Han FD, Yue J, Piao N, Wang RX, Zhou XQ, Xiao XZ et al: All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents.

Nature Energy 2019, 4(10):882-890.

43. Liu MJ, Xiao XZ*, Zhao SC, Chen M, Mao JF, Luo BS, Chen LX: Facile synthesis of Co/Pd supported by few-walled carbon nanotubes as an efficient bidirectional catalyst for improving the low temperature hydrogen storage properties of magnesium hydride.

Journal of Materials Chemistry A 2019, 7(10):5277-5287.

学术兼职

1. 《Journal of Alloys and Compounds》国际学术期刊副主编

2. 《Journal of Alloys and Compounds Communications》国际学术期刊高级编辑

3. 《Journal of Magnesium and Alloys》国际学术期刊青年编委

4. 中国可再生能源学会氢能专业委员会委员

5. 中国动力工程学会工业气体专业委员会委员

6. 中国氚科学与技术会议学术委员会委员

7. 浙江省能源研究会储能技术专业委员会秘书长

招生招聘

课题组长期接收优秀本科生、推免硕士生/直博生（包括新能源、材料、化工、机械相关学科方向）；同时欢迎上述研究方向的青年才俊作为博士后、助理教授、副教授以及科研助理加盟团队（详见：https://ae.sysu.edu.cn/article/359）。